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Description of the videos |
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1. Bouncing Putty
2. Combustion of Silicone Rubber and Natural Rubber
3. Combustion of Silicone Fluid and Paraffin Oil
4. Impregnation of Aerated-Concrete Brick
5. Antifoams 1
6. Antifoams 2 (Paper Clip)
7. Hydrolysis of Chloromethylsilanes |
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1.
Bouncing Putty
- A ball of silicone rebounds to a great height
when bounced off the ground, whereas Plasticine does not.
- A rapid
blow with a hammer will barely deform the silicone ball, but will flatten
the Plasticine.
- When a length of silicone is quickly pulled apart, it
breaks cleanly into two pieces. However, if the silicone is pulled
apart so slowly that it
does not tear, it will stretch very far.
- When the silicone
ball is bounced off the ground, the “flubber” effect
is seen again.
- Time-lapse photography shows how the silicone ball
flows over a clock like honey. (It is reminiscent of a similar painting
by a famous surrealist
artist.)
Note: For a discussion and explanation of these observations, see
the "Viscoelasticity" experiment.
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2.
Combustion of Silicone Rubber and Natural Rubber
- A metal
plate supporting a piece of natural rubber and a piece of silicone
rubber side by side is heated with a Bunsen burner.
- The rubber soon starts to
decompose (vapors are emitted). The silicone rubber does not decompose.
- On
further heating, the natural rubber changes shape and color and eventually
catches fire. Silicone rubber does not change initially and only after
prolonged heating does it leave marks on the plate. It does not burn.
Note: For a discussion and explanation of these observations, see
the experiment "Flammability
of silicones in comparison with other polymers".
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3.
Combustion of Silicone Fluid and Paraffin Oil
- A metal plate is heated strongly with
two Bunsen burners. A drop each of paraffin oil and silicone fluid
are allowed to fall onto the heated
areas.
- The paraffin oil ignites immediately and burns quickly with an
orange flame. The silicone fluid does not ignite initially.
- Only after
a long time, when the plate has become very hot, does the silicone
fluid ignite and slowly burn with a dazzling flame.
- Whereas the paraffin oil
does not leave any residue behind on the plate after combustion, the
silicone fluid leaves a white solid (silicon
dioxide) behind.
Note: For a discussion and explanation of these observations, see the
experiment "Burning
of liquid silicones"
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4.
Impregnation of Aerated-Concrete Brick
- Drops of water are pipetted onto aerated concrete bricks, one treated
with silicone fluid, and the other untreated.
- Whereas the water seeps into the
untreated brick, it runs off the brick rendered water-repellent with
silicone fluid.
Note: For a discussion and explanation of these observations,
see Variant A and Variant
B of the "Hydrophobic properties
of silicone fluids" experiment.
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5.
Antifoams 1
- A soap solution in two glass beakers is stirred. When the stirrer
has been turned off, a layer of foam is seen in both beakers.
- Some antifoam
agent is now pipetted into one of the beakers. The foam collapses.
- The
contents of both beakers are stirred again. The soap solution containing
the antifoam will not foam even when stirred vigorously.
Note: For
a discussion and explanation of these observations, see the "Silicones
as antifoams" experiment.
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6.
Antifoams 2 (Paper Clip)
- Tweezers are used to carefully place a paper clip on the
surface of distilled water in a container. The paper clip floats
on the water.
- Distilled water is added dropwise from a pipet. The paper clip
continues to float.
- Drops of soap solution are now added. After just a
few drops, the paper clip sinks.
- The experiment is repeated. Instead of
soap solution, drops of a mixture of soap solution and silicone antifoam
agent are added. After a few drops,
the paper clip sinks to the bottom of the container.
Note: For a discussion
and explanation of these observations, see the "Silicones
as antifoams" experiment.
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7.
Hydrolysis of Chloromethylsilanes
Preparation
- 6 test tubes (TT) in a rack are filled as follows:
- TT No. 1: 4 ml distilled
water
- TT No. 2: 8 ml distilled water
- TT No. 3: 12 ml distilled water
- TT No. 4: 1 ml chlorotrimethylsilane
- TT No. 5: 1 ml dichlorodimethylsilane
- TT No. 6: 1 ml trichloromethylsilane
Procedure
- The contents of TT 1 are poured into TT 4. A reaction occurs
and the solution turns hazy. After the solution has been left for
a long while, two clear liquid phases separate out; the volume of the
upper layer is
smaller
than
the lower one.
- The contents of TT 2 are poured into TT 5.
A violent reaction occurs and the solution turns hazy. Two clear
liquid phases separate out
fairly rapidly; the volume of the upper layer is smaller than the lower one.
- The contents of TT 3 are poured into TT 6. A violent reaction occurs
and the solution turns very hazy. A white solid has formed.
- Some liquid
from the lower phases in TT 4 and TT 5 and from the liquid phase
of TT 6 is pipetted onto separate strips of indicator
paper. Each strip turns red.
Note: For an explanation and discussion of these
observations, see the experiments "Hydrolysis
of chloromethylsilanes" and "Rate
of hydrolysis of chloromethylsilanes". |
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